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Electrochemical Trifluoromethylselenolation of Activated Alkyl Halides

Abstract : A practical electrochemical method for the generation of CF3Se− anion from a shelf-stable reagent (TsSeCF3) is reported allowing the metal-free trifluoromethylselenolation of activated alkyl halides. Cyclic voltammetric and 19F NMR studies are also presented and allowed to gain insight into the reaction mechanism.
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https://hal.uvsq.fr/hal-03687668
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Submitted on : Friday, June 3, 2022 - 2:42:38 PM
Last modification on : Tuesday, October 18, 2022 - 4:30:40 AM

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Kevin Grollier, Clément Ghiazza, Anis Tlili, Thierry Billard, Maurice Médebielle, et al.. Electrochemical Trifluoromethylselenolation of Activated Alkyl Halides. European Journal of Organic Chemistry, 2022, 2022 (19), ⟨10.1002/ejoc.202200123⟩. ⟨hal-03687668⟩

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